Selective synthesis of secondary amines from nitriles using Pt nanowires as a catalyst.

نویسندگان

  • Shuanglong Lu
  • Jiaqing Wang
  • Xueqin Cao
  • Xinming Li
  • Hongwei Gu
چکیده

A new one-pot method has been developed for the selective synthesis of secondary amines via reductive amination of the corresponding nitriles using Pt nanowires as a catalyst. This method allows for the synthesis of both unsymmetrical and symmetrical secondary amines in excellent yields (up to 95%) in the presence or absence of additional amines, respectively. Furthermore, the reaction proceeds under mild conditions and is environmentally benign.

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عنوان ژورنال:
  • Chemical communications

دوره 50 26  شماره 

صفحات  -

تاریخ انتشار 2014